Optimization of solutions of polyamide for AC electrospinning

dc.contributorSkřivánek Josef, Ing. Ph.D. : 63445
dc.contributor.advisorKalous Tomáš, Ing. Ph.D. : 63777
dc.contributor.authorSangave, Ulhas Balasaheb
dc.date.accessioned2022-12-19T04:46:45Z
dc.date.available2022-12-19T04:46:45Z
dc.date.committed2022-5-16
dc.date.defense2022-06-15
dc.date.issued2022-06-15
dc.date.submitted2021-11-1
dc.date.updated2022-6-15
dc.degree.levelIng.
dc.description.abstractNowadays, nanofibers and nanoparticles have become the attraction of study for researchers. Due to the unique physical properties such as ultra-thin fiber diameter. The electrospinning manufacturing technique produces nanofibers that have potential applications in the electronic, biomedical, and filtration industries. Until today, plenty of polymers has been electrospun into nanofibers. Researchers are trying to find the finest nanofibers with excellent spinnability on electrospinning.This study's goal was to optimize the solution for polyamides on alternating current (AC) electrospinning. The polymers PA 6 and PA 6,12 have been chosen for the study. These polymers were dissolved in the mixture of formic acid and dichloromethane at a weight ratio of 1:1 with an increasing concentration of sulfuric acid. All the solutions were electrospun on the alternating and direct current electrospinning systems. The solubility and spinnability of polyamides were investigated. The scanning electron microscope was used for nanofiber diameter measurement. The solution parameters, such as surface tension, conductivity, and viscosity, were measured to see the impact of acid content on the mixture.All the prepared polyamide solutions were spun on both AC and DC electrospinning systems. The sulfuric acid concentration influences the spinnability, nanofiber diameter, and solution properties. AC and DC electrospun polyamide nanofibrous structures are different in terms of bulkiness or thickness.cs
dc.description.abstractNowadays, nanofibers and nanoparticles have become the attraction of study for researchers. Due to the unique physical properties such as ultra-thin fiber diameter. The electrospinning manufacturing technique produces nanofibers that have potential applications in the electronic, biomedical, and filtration industries. Until today, plenty of polymers has been electrospun into nanofibers. Researchers are trying to find the finest nanofibers with excellent spinnability on electrospinning.This study's goal was to optimize the solution for polyamides on alternating current (AC) electrospinning. The polymers PA 6 and PA 6,12 have been chosen for the study. These polymers were dissolved in the mixture of formic acid and dichloromethane at a weight ratio of 1:1 with an increasing concentration of sulfuric acid. All the solutions were electrospun on the alternating and direct current electrospinning systems. The solubility and spinnability of polyamides were investigated. The scanning electron microscope was used for nanofiber diameter measurement. The solution parameters, such as surface tension, conductivity, and viscosity, were measured to see the impact of acid content on the mixture.All the prepared polyamide solutions were spun on both AC and DC electrospinning systems. The sulfuric acid concentration influences the spinnability, nanofiber diameter, and solution properties. AC and DC electrospun polyamide nanofibrous structures are different in terms of bulkiness or thickness.en
dc.description.mark3
dc.format75 p.
dc.format.extent
dc.identifier.signatureV 202204529
dc.identifier.urihttps://dspace.tul.cz/handle/15240/166766
dc.language.isoan
dc.relation.isbasedonpar1. M. Ventra, Introduction to nanoscale science and technology, Springer, 2004, ISBN: 978-1-4020-7757-9par par2. S. Ramakrishna, An introduction to electrospinning and nanofibers, World scientific, 2005, ISBN: 978-981-4479-77-6par par3. T. Kalous, Improved spinnability of PA 6 solutions, Elsevier, 2020, DOI:~10.1016/j.matlet.2020.128761~par
dc.rightsVysokoškolská závěrečná práce je autorské dílo chráněné dle zákona č. 121/2000 Sb., autorský zákon, ve znění pozdějších předpisů. Je možné pořizovat z něj na své náklady a pro svoji osobní potřebu výpisy, opisy a rozmnoženiny. Jeho využití musí být v souladu s autorským zákonem https://www.mkcr.cz/assets/autorske-pravo/01-3982006.pdf a citační etikou https://knihovna.tul.cz/document/26cs
dc.rightsA university thesis is a work protected by the Copyright Act. Extracts, copies and transcripts of the thesis are allowed for personal use only and at one?s own expense. The use of thesis should be in compliance with the Copyright Act. https://www.mkcr.cz/assets/autorske-pravo/01-3982006.pdf and the citation ethics https://knihovna.tul.cz/document/26en
dc.rights.urihttps://knihovna.tul.cz/document/26
dc.rights.urihttps://www.mkcr.cz/assets/autorske-pravo/01-3982006.pdf
dc.subjectNanofiberscs
dc.subjectelectrospinningcs
dc.subjectpolyamidecs
dc.subjectAC and DC electrospinningcs
dc.subjectsolutioncs
dc.subjectadditivecs
dc.subjectNanofibersen
dc.subjectelectrospinningen
dc.subjectpolyamideen
dc.subjectAC and DC electrospinningen
dc.subjectsolutionen
dc.subjectadditiveen
dc.titleOptimization of solutions of polyamide for AC electrospinningcs
dc.titleOptimization of solutions of polyamide for AC electrospinningen
dc.typediplomová prácecs
local.degree.abbreviationNavazující
local.degree.disciplineNTNA
local.degree.programmeTextile Engineering
local.degree.programmeabbreviationN0723A270002
local.department.abbreviationKNT
local.facultyFakulta textilnícs
local.faculty.abbreviationFT
local.identifier.authorT19000390
local.identifier.stag44131
local.identifier.verbis
local.identifier.verbisf6195d2e-7406-4ac8-8e51-d58af06178ca
local.note.administratorsautomat
local.note.secrecyPovoleno ZverejnitPraci Povoleno ZverejnitPosudky
local.poradovecislo4529
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