The influence of crystalline water on signals of nqr and NMR in Na2PtCl6.6H2O

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dc.contributor.authorHaleš, J.
dc.contributor.authorRákoš, Matej
dc.contributor.authorLasanda, J.
dc.contributor.authorJankuba, J.
dc.contributor.authorBelica, C.
dc.contributor.authorFischer, Volker
dc.date.accessioned2016-07-08
dc.date.available2016-07-08
dc.date.issued1982
dc.description.abstractThe method for preparation of samples of paramagnetic hydrates Na2PtCl6.nH2O (O ≤ n ≤ 6 ) is described in detail with analysis of NQR and NMR spectra versus number of molecules of crystalline water, Samples were dehydrated and controlled by means of derivatograph, with simultaneous measurements of NQR and NMR signals. The investigation was concerned with parameters of intensity and line width. As we found out, line width of NMR signals was constant and that indicates that packing and structure of crystalline water doesn't change with amount of crystalline water. On the contrary, from increase of line width of NQR spectra with decrease of n for crystalline water we concluded of successive degradation of occahedric structure of Na2PtCl6.nH2O, with total collapse for n = O. © 1982.en
dc.formattext
dc.identifier.doi10.1016/0022-2860(82)85157-0
dc.identifier.issn0022-2860
dc.identifier.scopus2-s2.0-49049129749
dc.identifier.urihttps://dspace.tul.cz/handle/15240/16570
dc.identifier.urihttps://www.sciencedirect.com/science/article/abs/pii/0022286082851570?via%3Dihub
dc.language.isoen
dc.relation.ispartofJournal of Molecular Structure
dc.relation.ispartofJournal of Molecular Structureen
dc.sourcej-scopus
dc.sourcej-wok
dc.titleThe influence of crystalline water on signals of nqr and NMR in Na2PtCl6.6H2Oen
dc.typearticle
local.accessaccess
local.citation.epage72
local.citation.spage69
local.departmentDepartment of Physics
local.facultyFaculty of Sciences, Humanities and Education
local.identifier.codenJMOSB
local.identifier.wokA1982PH59300007
local.notenefunguje RIV
local.relation.issueC
local.relation.volume83
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Publikace 1982