Computer Estimation Of Dissociation-Constants 5. Regression-Analysis Of Extended Debye-Huckel Law

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dc.contributor.authorMeloun, Milan
dc.contributor.authorJavůrek, Milan
dc.contributor.authorMilitký, Jiří
dc.date.accessioned2016-07-08
dc.date.available2016-07-08
dc.date.issued1992
dc.description.abstractNonlinear regression program DHMINOPT has been used for an analysis of a set of values expressing the dependence of mixed dissociation constant on ionic strength according to the extended Debye-Hueckel law. Efficiency of program has been examined on simulated data loaded with generated random errors. Goodness-of-fit brings various regression diagnostics enabling to prove a reliability of a regression process and parameter estimates. For five selected sulphonephtalein indicators, i.e. Bromocresol Green, Bromophenol Red, Bromocresol Purple, Bromothymol Blue and Phenol Red, the thermodynamic dissociation constant has been determined at 25-degrees-C together with the ion-size parameter and the salting-out coefficient.en
dc.formattext
dc.identifier.doi10.1007/BF01242477
dc.identifier.issn0026-3672
dc.identifier.urihttps://dspace.tul.cz/handle/15240/16546
dc.language.isoen
dc.publisherSpringer-Verlag Wien
dc.relation.ispartofMikrochimica Acta
dc.sourcej-wok
dc.subjectDISSOCIATION CONSTANTSen
dc.subjectPROTONATION EQUILIBRIAen
dc.subjectPROTONATION CONSTANTSen
dc.subjectDEBYE-HUCKEL LAWen
dc.subjectION-SIZE PARAMETERen
dc.titleComputer Estimation Of Dissociation-Constants 5. Regression-Analysis Of Extended Debye-Huckel Lawen
dc.typearticle
local.accessaccess
local.citation.epage231
local.citation.spage221
local.departmentDepartment of Textile Materials
local.facultyFaculty of Textile Engineering
local.fulltextyes
local.identifier.wokA1992KE27100004
local.notenefunguje RIV
local.relation.issue5.6.2016
local.relation.volume109
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