Morphology, structure and photowettability of TiO2 coatings doped with copper and fluorine

dc.contributor.authorSobczyk-Guzenda Annacs
dc.contributor.authorOwczarek S.cs
dc.contributor.authorFijalkowski Mateuszcs
dc.contributor.authorBatory Damiancs
dc.contributor.authorGazicki-Lipman M.cs
dc.date.accessioned2018-09-25T12:13:45Z
dc.date.available2018-09-25T12:13:45Z
dc.date.issued2018cs
dc.description.abstractThe work reports synthesis, structure and properties of doubly doped titanium dioxide coatings activated by ultraviolet and visible light. Copper within a concentration range of 0.4–3.4 at% and fluorine within a concentration range of 1.7–9.4 at% were introduced as dopants. The coatings were prepared with the help of radiofrequency plasma enhanced chemical vapor deposition technique with a single precursor compound providing both dopants and titanium (IV) chloride being a source of titanium. Elemental composition and chemical bonding analyses of the coatings were carried out with the help of X-ray photoelectron spectroscopy. The results indicate that both admixtures are chemically bound to the TiO2 matrix – a notion confirmed by Fourier transform infrared spectroscopy. Phase composition studies, performed with a low angle X-ray diffraction method, revealed a presence of a threshold concentration of the dopants affecting the coatings crystallinity. Surface morphology and its topography were studied with the help of scanning electron microscopy and atomic force microscopy. Several coatings exhibited a superhydrophilic effect upon relatively short time of illumination.en
dc.format.extent10cs
dc.identifier.doi10.1016/j.ceramint.2017.12.107
dc.identifier.issn0272-8842cs
dc.identifier.urihttps://dspace.tul.cz/handle/15240/31152
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0272884217328146?via%3Dihub
dc.language.isoengcs
dc.publisherElsevier BVcs
dc.relation.ispartofseries1cs
dc.relation.urihttp://www.sciencedirect.com/science/article/pii/S0272884217328146?via=ihubcs
dc.subjectCu and F doped TiO2cs
dc.subjectRF PECVD methodcs
dc.subjectRutilecs
dc.subjectPhoto-wettingcs
dc.subjectOptical propertiescs
dc.titleMorphology, structure and photowettability of TiO2 coatings doped with copper and fluorineen
dc.titleMorphology, structure and photowettability of TiO2 coatings doped with copper and fluorinecs
local.citation.epage5076-5085cs
local.citation.spage5076-5085cs
local.identifier.publikace4610
local.identifier.wok425204400072en
local.relation.issue5cs
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