Novel chapter in hybrid materials: One-pot synthesis of purely organosilane fibers

Simple item page
dc.contributor.authorHolubová, Barbora
dc.contributor.authorMáková, Veronika
dc.contributor.authorMüllerová, Jana
dc.contributor.authorBrus, Jiří
dc.contributor.authorHavlíčková, Kristýna
dc.contributor.authorJenčová, Věra
dc.contributor.authorMichalcová, Alena
dc.contributor.authorKulhánková, Johana
dc.contributor.authorŘezanka, Michal
dc.date.accessioned2020-03-23T17:17:04Z
dc.date.available2020-03-23T17:17:04Z
dc.date.issued2020-03
dc.description.abstractDespite the extensive literature on organosilane hybrid materials, there are very few reports on the preparation of purely organosilane non-woven fibrous mats. Nevertheless, their use in various application fields may be of great importance regarding the global issue of polymer fibers and the toxicity of other compounds used so far in the composite polymer-organosilane fiber-manufacturing process. The greatest obstacle seems to be the supposed difficulty in the polymerization of organosilanes in a spinnable polymeric solution. In this work, we report the one-pot synthesis of electrospun organosilane fibers without any kinds of surfactants, low-molecular-weight polymeric gelators or spinnable polymers. The purely organosilane fibrous mats were prepared only via a suitable adjustment of the sol-gel processing parameters and were successfully produced an industrial electrospinning device, promising possible fabrication on a large scale. Moreover, the use of two differently-structured model benzene functionalized organoalkoxysilanes proves the possibility of designing a molecularly engineered material tailored to specific applications. These organosilane fibrous mats seem to be promising in various application fields, such as reusable catalysts, adsorption or conducting membranes or as novel biomaterials. This latter of these areas was preliminarily studied herein.cs
dc.format.extent10 strancs
dc.identifier.doi10.1016/j.polymer.2020.122234
dc.identifier.issn323861
dc.identifier.orcid0000-0001-9719-6588 Máková, Veronika
dc.identifier.orcid0000-0002-1094-5169 Müllerová, Jana
dc.identifier.orcid0000-0001-7391-9526 Jenčová, Věra
dc.identifier.orcid0000-0002-7390-1243 Řezanka, Michal
dc.identifier.urihttps://dspace.tul.cz/handle/15240/154641
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0032386120300768
dc.language.isocscs
dc.publisherElsevier Ltd
dc.relation.ispartofPolymer
dc.subjectElectrospinning
dc.subjectOne-pot synthesis
dc.subjectOrganic-inorganic hybrids
dc.subjectOrganosilane fibers
dc.subjectSol-gel process
dc.titleNovel chapter in hybrid materials: One-pot synthesis of purely organosilane fiberscs
local.article.number122234
local.identifier.publikace7138
local.relation.issue2
local.relation.volume190
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Novel chapter in hybrid materials.pdf
Size:
1.62 MB
Format:
Adobe Portable Document Format
Description:
článek
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections