Co-solvent free interfacial polycondensation and properties of polyurea PCM microcapsules with dodecanol dodecanoate as core

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dc.contributor.authorCai, Changwei
dc.contributor.authorOuyang, Xu
dc.contributor.authorZhou, Lan
dc.contributor.authorLiu, Guojin
dc.contributor.authorWang, Yan
dc.contributor.authorZhu, Guocheng
dc.contributor.authorYao, Juming
dc.contributor.authorMilitký, Jiří
dc.contributor.authorVenkataraman, Mohanapriya
dc.contributor.authorZhang, Guoqing
dc.date.accessioned2020-03-10T07:33:56Z
dc.date.available2020-03-10T07:33:56Z
dc.date.issued2020-03
dc.description.abstractA kind of eco-friendly micro-encapsulated phase change materials (MEPCM) with dodecanol dodecanoate as core material were synthesized via the interfacial polymerization of toluene-2, 4-diisocyanate (TDI) and diethylenetriamine (DETA). During the preparation, a facile solvent free synthesis route was developed owing to the good compatibility of TDI and dodecanol dodecanoate. The synthesized MEPCM were characterized by Field Emission Scanning Electron Microscopy (FE-SEM), Particle Size Distribution (PSD) analyzer, Differential Scanning Calorimetry (DSC), Thermogravimetric/Infrared spectrometry (TG-IR) and thermal constants analyzer. It is found that the resultant MEPCM in nearly spherical shape are in the size scope from 10.0 to 40.0 μm, have the average latent heat in the range of 103.4–140.3 J/g, and exhibit high temperature resistance with an onset evaporation temperature at 234.0 °C. Moreover, the MEPCM possess good thermal conductivity from 0.17 W/m K to 0.21 W/m K. Therefore, it is confirmed that the prepared MEPCM can be regarded as a promising thermal energy storage material appropriate to the thermo-regulating fields such as renewable solar heating system.cs
dc.format.extent10 strancs
dc.identifier.WebofScienceResearcherIDO-6270-2015 Venkataraman, Mohanapriya
dc.identifier.doi10.1016/j.solener.2020.02.071
dc.identifier.issn0038092X
dc.identifier.orcid0000-0002-8977-1244 Venkataraman, Mohanapriya
dc.identifier.urihttps://dspace.tul.cz/handle/15240/154620
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0038092X20301985
dc.language.isocscs
dc.publisherElsevier Ltd
dc.relation.ispartofSolar Energy
dc.subjectDodecanol dodecanoatecs
dc.subjectPhase change microcapsulescs
dc.subjectPolyureacs
dc.subjectThermal propertycs
dc.titleCo-solvent free interfacial polycondensation and properties of polyurea PCM microcapsules with dodecanol dodecanoate as corecs
local.citation.epage730
local.citation.spage721
local.relation.volume199
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