Cyclodextrin-Functionalised Nanomaterials for Enantiomeric Recognition

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dc.contributor.authorHobbs Christophercs
dc.contributor.authorŘezanka Pavelcs
dc.contributor.authorŘezanka Michalcs
dc.date.accessioned2020-06-08T09:51:57Z
dc.date.available18-39-2020en
dc.date.available2020-06-08T09:51:57Z
dc.date.issued2020cs
dc.date.updated18-45-2020en
dc.description.abstractCyclodextrins, which are glucose-based cyclic oligosaccharides, are materials that can act inherently as chiral selectors, with many reports of the application of cyclodextrins in enantioseparation. However, many studies have encountered the problem of insufficient enantioselective performance of the chiral selector. One of the main reasons is due to low surface concertation's, whereby interaction between the chiral selector and analyte usually occurs at a surface. Thus, scientists have been trying for the last two decades to overcome this problem, with the incorporation of nanomaterials being promising as they possess a large surface area which allows for the accommodation of a higher concentration of the chiral selectors. Herein, we outline nanomaterial-cyclodextrin conjugates that work in tandem to achieve or enhance enantioselectivity through various methods such as chromatography, adsorption, and removal using magnetic nanoparticles, or enantiorecognition using electrochemical techniques.
dc.format.extent13cs
dc.identifier.doi10.1002/cplu.202000187
dc.identifier.issn2192-6506cs
dc.identifier.orcid0000-0002-7390-1243 Řezanka Michal
dc.identifier.orcid0000-0002-5456-5301 Hobbs Christopher
dc.identifier.urihttps://dspace.tul.cz/handle/15240/156838
dc.identifier.urihttps://pubmed.ncbi.nlm.nih.gov/32391654/
dc.language.isoengcs
dc.publisherWileycs
dc.relation.ispartofChemPlusChemen
dc.relation.ispartofseries1cs
dc.relation.urihttps://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cplu.202000187cs
dc.subjectchiral resolutioncs
dc.subjectcyclodextrinscs
dc.subjectenantiomerscs
dc.subjectnanomaterialscs
dc.subjectrecognitioncs
dc.titleCyclodextrin-Functionalised Nanomaterials for Enantiomeric Recognitioncs
dc.typeReview
local.citation.epage876-888cs
local.citation.spage876-888cs
local.identifier.publikace7673
local.relation.issue5cs
local.relation.issue5
local.relation.issue
local.relation.volume85
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