The influence of crystalline water on signals of nqr and NMR in Na2PtCl6.6H2O

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Show simple item record Haleš, J. Rákoš, Matej Lasanda, J. Jankuba, J. Belica, C. Fischer, Volker 2016-07-08 2016-07-08 1982
dc.identifier.issn 0022-2860
dc.description.abstract The method for preparation of samples of paramagnetic hydrates Na2PtCl6.nH2O (O ≤ n ≤ 6 ) is described in detail with analysis of NQR and NMR spectra versus number of molecules of crystalline water, Samples were dehydrated and controlled by means of derivatograph, with simultaneous measurements of NQR and NMR signals. The investigation was concerned with parameters of intensity and line width. As we found out, line width of NMR signals was constant and that indicates that packing and structure of crystalline water doesn't change with amount of crystalline water. On the contrary, from increase of line width of NQR spectra with decrease of n for crystalline water we concluded of successive degradation of occahedric structure of Na2PtCl6.nH2O, with total collapse for n = O. © 1982. en
dc.format text
dc.language.iso en
dc.relation.ispartof Journal of Molecular Structure
dc.relation.ispartof Journal of Molecular Structure en
dc.source j-scopus
dc.source j-wok
dc.title The influence of crystalline water on signals of nqr and NMR in Na2PtCl6.6H2O en
dc.type article
dc.identifier.doi 10.1016/0022-2860(82)85157-0
local.relation.volume 83
local.relation.issue C
local.identifier.wok A1982PH59300007
local.identifier.scopus 2-s2.0-49049129749
local.faculty Faculty of Sciences, Humanities and Education
local.citation.spage 69
local.citation.epage 72
local.identifier.coden JMOSB
local.department Department of Physics
local.access access
local.note nefunguje RIV

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